What you need to do there is to modify the workitem in question and add the values that you would like to use. There are many posts out there on the topic. I would also look to MSDN for Process Template Customizations.
You do not actually modify the sql tables. This will get handled when you import the new workitem. You will want to get familiar with the WITexport and WITImport commands.These command line utilities allow you to export and import the workitem that you are looking to modify.
-paul
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