Hi, well there is nothing directly to send SMS in .NET framework, so first of all you will need to contact a provider to get access to some components or webservices for using it to send, usually mobile provider companies has something, so ask mobile providers in your country.
After that it will be just using that webservice or component.
Anyway, for this kind of questions is better to go to the VB.NET development forums, where you will get lot of VB.NET help, as this forum is related only for Team System issues.
Good luck.
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